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Graminaceous plants secrete a family of small molecules called mugineic acid family phytosiderophores (MAs), to solubilize soil Fe (Takagi 1976)

It catalyzes the esterification of long-chain polyunsaturated fatty acids (PUFAs, (e.g., arachidonic acid) into membrane phospholipids, making them substrates for peroxidation by enzymes like lipoxygenases (ALOXs) ( 2+ , is an essential catalyst for ferroptosis via the Fenton reaction

c Methionine side chain (-CH 2 -CH 2 -S-CH 3 ) replaced by the norleucine (Nle) side chain (-CH 2 -CH 2 -CH 2 -CH 3 )

They found that BHB inhibits HDAC3 binding to the Claudin-5 promoter under high glucose (HG) conditions