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Glutathione, a tripeptide, contains a normal peptide bond (between cysteine and glycine) and an isopeptide bond (between glutamate and cysteine)

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Plant J 54:10631075 Gromes R, Hothorn M, Lenherr ED, Rybin V, Scheffzek K, Rausch T (2008b) The redox switch of gamma- glutamylcysteine ligase via a reversible monomer-dimer transition is a mechanism unique to plants

[] IL-6 derived from the skeletal muscle signals to signal transducer transducer and activator of transcription 3 (STAT3)-mediated transcriptional suppression of gluconeogenic program, and thus, blunts hepatic glucose production