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PMID: 139 AggarwalAUpadhyayR

Health effect of agricultural pesticide use in China: Implications for the development of GM crops

Boc-SPPS provided the linear peptide C -terminal thioester, which underwent NCL in solution upon unmasking of the d-1,3-thiazolidine-4-carboxylic acid (d-Thz) to give the N -terminal Cys, followed by adjustment to pH 7.5, affording the cyclic peptide 51 in 38% yield